电位对天然黄铜矿表面膜层性质的影响

采用循环伏安（CV）、扫描电子显微镜（SEM）和电化学阻抗谱（EIS）研究黄铜矿在含有5×10-4mol/L乙黄药溶液中的电化学行为以及电位对黄铜矿表面膜层成分和性质的影响。结果表明：在开路电位（OCP）下,天然黄铜矿表面发生黄药阴离子的吸附过程;在阳极电位范围-0.11～0.2V内,主要发生黄药阴离子氧化形成疏水双黄药膜层的电化学过程。形成的双黄药膜层在电位为0V时具有较高覆盖度和较大的厚度,随着电位的增加表面双黄药膜层的覆盖度和厚度减小。当电位高于0.2V时,黄铜矿表面发生以自身活化溶解为主的电化学过程,黄铜矿表面由双黄药膜层转化成为大量具有多孔和疏松结构的含有Cu（Ⅱ）和Fe（Ⅲ）的氧化物。     

具有不同壁厚的金属型近共晶Al-Si合金铸件的自退火效应(英文)

为了揭示冷却速度对铝硅合金中β相的大小及分布的影响,研究其凝固过程中的自退火效应,设计了一套实验装置并进行实验。对铝硅合金试样的不同壁厚部位中的β相特征进行研究。研究发现,其颗粒的尺寸分布符合对数正态分布。为了研究不同壁厚处以及不同冷却条件下的性能,还进行了布氏硬度实验。实验表明,试样在水中冷却时其硬度比在空气中冷却时更均匀,并且其平均硬度更高。     

基于密度泛函理论计算的3d过渡金属掺杂CuGaS2电子结构分析

3d transition metals doped CuGaS2 are considered as possible absorbing material candidates for intermediated band thin film solar cells. The electronic structure and optical properties of 3d transition metals doped CuGaS2 are investigated by using density functional theory calculations with the GGA ＋ U method in the present work. The doping with 3d transition metals does not obviously change the crystal structure, band gap, and optical absorption edge of the CuGaS2 host. However, in the case of CuGa1-χTMχS2 （TM = Ti, V, Cr, Fe, and Ni）, there is at least one distinct isolated impurity energy level in the band gap, and the optical absorption is enhanced in the ultraviolet-light region. Therefore, these materials are band thin film solar ceils. The calculated results are very well better explain them. ideal absorber material candidates for intermediated consistent with experimental observations, and could better explain them.     

噪声调频信号的仿真技术

基于噪声调频的原理,主要分析了噪声调频信号中的多目标、等间隔谱和不等间隔谱信号的建模方法,给出了各种噪声调频信号的时域表达式,利用MATLAB对以上模型进行了仿真,进而得到了它们的频谱图。最后根据频谱图,探讨了各种噪声调频信号的特点。     

A novel image segmentation model with an edge weighting function

A variational model for image segmentation consists of a data term and a regularization term. Usually, the data term is chosen as squared $\text{ L }_{2}$ norm, and the regularization term is determined by the prior assumption. In this paper, we present a novel model in the framework of MAP (maximum a posteriori). A new iteratively reweighted $\text{ L }_{2}$ norm is used in the data term, which shares the advantages of $\text{ L }_{2}$ and mixed $\text{ L }_{21}$ norm. An edge weighting function is addressed in the regularization term, which enforces the ability to reduce the outlier effects and preserve edges. An improved region-based graph cuts algorithm is proposed to solve this model efficiently. Numerical experiments show our method can get better segmentation results, especially in terms of removing outliers and preserving edges.     

点聚焦透镜天线焦斑附近波长延长

利用简易装置搭建“测量线”系统,采用驻波法测量了点聚焦透镜天线焦斑附近轴线上不同位置处的波长λF,与自由空间中的波长λ0相比,找出λF随轴向距离变化而变化的关系,并对该变化进行定性分析。通过对2种点聚焦透镜天线的测量,发现焦斑附近的波长λF较之自由空间中的波长λ0有0~5%的延长,且延长量随离焦点距离的增大而减小。最后对测试系统的精确度和误差源进行了分析。     

基于多元LDPC码译码算法研究的Qt设计与实现

为了实现Qt对多元LDPC码译码算法理论测试的界面操控,在多元LDPC码译码算法研究的基础上设计了Qt程序,用Matlab实现基本仿真,将其编译成可供Qt调用的动态链接库文件(dll)并进行调用,最终实现了该Qt界面对译码理论测试的直观操控,并进一步分析了译码数据。     

Towards High Efficiency and Low Roll‐Off Orange Electrophosphorescent Devices by Fine Tuning Singlet and Triplet Energies of Bipolar Hosts Based on Indolocarbazole/1, 3, 5‐Triazine Hybrids

Orange‐emitting phosphorescent organic light‐emitting diodes (PHOLEDs) are drawing more and more attention; however, high‐performance hosts designed for orange PHOLEDs are rare. Here, four indolocarbazole/1, 3, 5‐triazine hybrids are synthesized to optimize the singlet and triplet energies, as well as transporting properties, for ideal orange PHOLEDs. By introducing moieties with different electronegativity, a graded reduction of the singlet and triplet energies is achieved, resulting in minimum injection barrier and minimum energy loss. Besides, the charge transporting abilities are also tuned to be balanced on the basis of the bipolar features of those materials. The optimized orange PHOLED shows a maximum external quantum efficiency (EQE) of 24.5% and a power efficiency of 64 lm W^–1, both of which are among the best values for orange PHOLEDs. What is more, the efficiency roll‐off is extremely small, with an EQE of 24.4% at 1000 cd m^–2 and 23.8% at 10 000 cd m^–2, respectively, which is the lowest efficiency roll‐off for orange PHOLEDs to date, resulting in the highest EQE for orange PHOLEDs when the luminance is above 1000 cd m^–2. Besides the balanced charges, the small roll‐off is also attributed to the wide recombination zone resulting from the bipolar features of the hosts.     

Crystal Size,Morphology, and Growth Mechanism in Bio‐Inspired Apatite Nanocrystals

Bio‐inspired apatite nanoparticles precipitated in the presence of citrate ions at increasing maturation times are characterized in terms of structure, size, morphology, and composition through advanced X‐ray total scattering techniques. The origin of the platy crystal morphology, breaking the hexagonal symmetry, and the role of citrate ions is explored. By cross‐coupling the size and shape information of crystal domains with those obtained by atomic force microscopy on multidomain nanoparticles, a plausible mechanism underlying the amorphous‐to‐crystal transformation is reconstructed. In the present study, citrate plays the distinct roles of inducing the platy morphology of the amorphous precursor and controlling the thickness of the Ca‐deficient apatite nanocrystals. These findings can open new scenarios also in bone mineralization, where citrate might have a broader role to play than has been thought to date.     

A Complete Separation of Hexane Isomers by a Functionalized Flexible Metal Organic Framework

The separation ability of branched alkane isomers (nHEX, 3MP, 22DMB) of the flexible and functionalized microporous iron(III) dicarboxylate MIL‐53(Fe)‐(CF₃)₂ solid is evaluated through a combination of breakthrough experiments (binary or ternary mixtures), adsorption isotherms, X‐ray diffraction temperature analysis, quasi‐elastic neutron scattering measurements and molecular dynamics simulations. A kinetically controlled molecular sieve separation between the di‐branched isomer of hexane 22DMB from a mixture of paraffins is achieved. The reported total separation between mono‐ and di‐branched alkanes which was neither predicted nor observed so far in any class of porous solids is spectacular and paves the way towards a potential unprecedented upgrading of the RON of gasoline.